4-membered phosphorus heterocyclic compounds + organophosphorus compounds (with CD)

This set of materials includes books and CDs, a total of 2 sets, costing 270 yuan, including shipping fees. For more details, please consult the customer service staff. Phone numbers: 010-51654247, 010-57923471.

First set of materials: "Organophosphorus Compounds" latest published book by the publisher

Second set of materials: "Comprehensive Collection of Various Organophosphorus Compounds" CD, which includes content corresponding to the following categories, covering almost all aspects of this field, all compiled together;

Book Introduction, the table of contents is as follows:

Chapter 1 Introduction to Organophosphorus Compounds 1
1.1 Advances in Organophosphorus Chemistry 1
1.2 Structural Characteristics of Phosphorus Atoms and Types of Reactions with Organophosphorus Compounds 9
1.2.1 Atomic Properties and Electronegativity Characteristics of Phosphorus 9
1.2.2 Characteristics of the electron orbits of phosphorus atoms 9
1.2.3 The special stability of the phosphoryloyl bond (PO) 10
1.2.4 Typical Properties and Reaction Types of Organophosphorus Compounds 11
1.3 Classification and Nomenclature of Organophosphorus Compounds 14
1.3.1 Classification of Organophosphorus Compounds 14
1.3.2 Nomenclature of Organophosphorus Compounds 15
1.4 Spectral Characteristics of Organophosphorus Compounds 20
1.4.1 Infrared (IR) Spectral Characteristics 20
1.4.2 Characteristics of Organophosphorus Compounds in Nuclear Magnetic Resonance (NMR) Spectroscopy 22
1.5 Characteristics of Bond Energy and Bond Length of Organophosphorus Compounds27
1.5.1 Bond Energy: 27
1.5.2 Key length: 28
Reference 29

Chapter 2 Organic Phosphorus Compounds Containing P—H, P—C Single Bonds 31
2.1 Phosphine Compounds 31
2.1.1 Structural Characteristics of Phosphine Compounds and Main Physical and Chemical Parameters 31
2.1.2 Reactions of Phosphine Compounds 33
2.1.3 Methods for preparing phosphine compounds and their derivatives 39
2.1.4 Examples of the Preparation of Typical Phosphine Compounds 40
2.1.5 Applications of Phosphine Compounds 43
2.1.6 Toxicity and Safety 57
2.2 Phosphorus-containing Heterocyclic Compounds 57
2.2.1 Phospholene compounds 57
2.2.2 Phosphorocyclepentane compounds 61
2.2.3 Synthesis of Non-Aromatic Six-Membered Phosphorus Heterocycles 62
2.2.4 Tetrahedral Phosphorus Heterocyclic Compounds 67
2.2.5 Phosphorus-containing heterocyclic aromatic compounds 69
Reference 74

Chapter 3 Phosphorus-carbon Repeating Bonds in Phosphine Compounds 78
3.1 Phosphinylethylene compounds 78
3.1.1 Physical Properties of Phosphinyl Compounds 78
3.1.2 The Chemical Properties of Phosphinyl Compounds 79
3.1.3 Synthesis of Phosphinyl Compounds 85
3.1.4 Applications of Phosphinyl Compounds 87
3.2 Phosphinylalkyne compounds 88
3.2.1 Physical Properties of Phosphinylalkyne Compounds 88
3.2.2 Synthesis Methods of Phosphinylalkyne Compounds 90
3.2.3 The Chemical Properties of Phosphinylalkyne Compounds 92
Reference 102

Chapter 4 Salts and Phosphine Esters 103
4.1 Salt 103
4.1.1 Physical Properties of Salt 103
4.1.2 Chemical Properties of Salt 104
4.1.3 Synthesis of Salt 106
4.1.4 Uses of Salt 108
4.2 Phosphineyl Halides and Wittig Reaction 108
4.2.1 Physical Properties of Phosphoryl Halides 108
4.2.2 The Chemical Properties of Phosphoroyl Halides 109
4.2.3 Synthesis of phosphonium ylides 111
4.2.4 Wittig Reaction 113
4.2.5 Applications of the Wittig Reaction 114
4.2.6 Preparation of phosphynyl nitriles and examples of Wittig reactions 121
4.2.7 Improved Wittig Reaction (Wittig-Hornor Reaction) 122
4.3 Three-coordination Five-valence (σ3λ5) Phosphorus-carbon Rebond Compound 124
4.3.1 Three-coordination five-valence (σ3λ5) phosphorus compounds 124
4.3.2 Five-valent (σ3λ5) phosphorus negative ion compounds 130
4.3.3 Three-coordination Five-valent (σ3λ5) Phosphinylalkyne 130
Reference 131

Chapter 5 Phosphorus-Nitrogen Compounds 133
5.1 Single and Double Coordination Trivalent Phosphorus Compounds 133
5.1.1 Single Coordination Trivalent Phosphorus Compounds 133
5.1.2 Iminophosphazene 134
5.1.3 Imidophosphine anion 137
5.2 Trivalent Phosphorus-Nitrogen Compounds with Three Ligands (Ⅲ) 138
5.2.1 Amino Phosphorus 138
5.2.2 Properties of Trivalent Phosphorus-Nitrogen Compounds with Three Ligands 138
5.2.3 Methods for the synthesis of trivalent phosphorus-nitrogen compounds with three coordination sites 138
5.3 Three-coordination Five-valent Phosphorus-Nitrogen Compounds (Ⅴ) 139
5.3.1 Monopolynitrilophosphononitrile N≡P(NR2)2139
5.3.2 Bisiminophosphanes RP(NR′)2, Iminophosphonic acids RP(O)(NR′)139
5.4 Four-coordination Phosphorus (V) Nitrogen Compounds 140
5.4.1 Monophosphazene R3PNR′140
5.4.2 Phosphoryliminamide and Bisphosphorylminate Ions 141
5.4.3 Phosphoramidates 142
5.5 Five-coordination Phosphorus (V) Nitrogen Compounds 142
5.6 Acyclic Phosphorus-Nitrogen Compounds 142
5.6.1 Trivalent Phosphorus(III) Compounds 142
5.6.2 Mixed Phosphorus (Ⅲ) - Phosphorus (Ⅴ) Compounds 143
5.7 Ringed Phosphorus-Nitrogen Compounds 143
5.7.1 Divalent Phosphorus 143
5.7.2 Trivalent Phosphorus (Ⅲ) Compounds 143
5.7.3 Four-coordination Phosphorus Compounds 143
5.8 Cyclophosphorazinone (Ⅴ) Compound 144
5.8.1 Physical Properties of Cyclophosphorazinene 144
5.8.2 The Chemical Properties of Cyclophosphorazinene 148
5.8.3 Synthesis of Cyclic Phosphorazenes 150
Reference 152

Chapter 6 Phosphorus-Oxygen Bonds in Organic Phosphorus Compounds 153
6.1 Oxide Phosphide 153
6.1.1 Physical Properties of Oxidophosphines 153
6.1.2 The Chemical Properties of Oxidophosphines 154
6.1.3 Preparation of Oxide Phosphides 155
6.1.4 Examples of the Preparation of Oxidophosphides 156
6.1.5 Applications of Oxidophosphides 157
6.2 Phosphorous Tristearate 158
6.2.1 Physical Properties of Phosphite Triester 158
6.2.2 The Chemical Properties of Phosphite Triesters 161
6.2.3 Synthesis Method of Phosphite Tristearate 172
6.2.4 Preparation Examples of Phosphite Triesters 173
6.2.5 The main applications of phosphite triester 175
6.3 Dialkyl phosphite 181
6.3.1 The structural characteristics and physical properties of dialkyl phosphites 181
6.3.2 The Chemical Properties of Phosphite Dialkyl Esters 182
6.3.3 Synthesis Methods of Dialkyl Phosphites 184
6.3.4 Examples of the Preparation of Dialkyl Phosphites 185
6.3.5 Applications of dialkyl phosphite esters 186
6.4 Phosphoric Acid and Its Derivatives 187
6.4.1 The structural characteristics and physical properties of phosphoric acid and its derivatives 187
6.4.2 The Chemical Properties of Phosphoric Acid and Its Derivatives 189
6.4.3 Methods for preparing phosphoric acid and its derivatives 196
6.4.4 The Main Applications of Phosphoric Acid and Its Derivatives 210
6.5 Phosphonic acids and their derivatives 212
6.5.1 The structural characteristics and physical properties of phosphonic acids and their derivatives 212
6.5.2 The Chemical Properties of Phosphonic Acids and Their Derivatives 214
6.5.3 Synthesis of phosphonic acids and their derivatives 215
6.5.4 Uses of phosphonic acids and their derivatives 225
6.5.5 Latest Research Progress on Phosphonic Acids and Their Derivatives 234
6.6 times (sub)phosphonic acids and their derivatives 234
6.6.1 Physical Properties of (Sub)Phosphate and Its Derivatives 235
6.6.2 Chemical Properties of (Sub)Phosphate Acids and Their Derivatives 236
6.6.3 Synthesis of (sub)phosphonic acids and their derivatives 240
6.6.4 Examples of the synthesis of (sub)phosphonic acids and their derivatives 247
6.6.5 Uses of (sub)phosphonic acids and their derivatives 248
6.7 times subphytates and their derivatives 249
6.7.1 Structure of Bisphosphonates 249
6.7.2 Chemical Properties of Subphytates 249
6.7.3 Synthesis of phosphinoacetates (geminal phosphine oxides) and their derivatives 250
6.7.4 Examples of the synthesis of midophosphates [93] 254
6.7.5 Examples of the application of phosphonoacetate as a ligand in catalysts 254
Reference 256

Chapter 7 Phosphorus-Sulfur and Phosphorus-Silicon Compounds 259
7.1 Sulfide Phosphate 259
7.1.1 The Structure and Physical Properties of Sulfide Phosphorus 259
7.1.2 The Chemical Properties of Sulfides 260
7.1.3 Methods for the synthesis of sulfophosphorus compounds 260
7.2 Phosphothioate Compounds 261
7.2.1 The Structure and Physical Properties of Phosphothioates 261
7.2.2 Chemical Properties of Phosphothioate Derivatives 261
7.2.3 Synthesis of Phosphothioate Derivatives 265
7.2.4 Applications of Thiophosphoric Acid Derivatives 269
7.3 Phosphorus-Silicon Compounds 270
7.3.1 Silicon replacing single phosphorus compounds 270
7.3.2 Silicon-containing polyphosphorus compounds 272
7.3.3 Ringed Phosphosilane Compound 273
7.3.4 Silicon-phosphorus double bonds, silicon-phosphorus (V) compounds, and silicon-phosphorus free radicals 273
Reference 273

Chapter 8 Phosphorus Compounds Containing PP (As) Bonds 275
8.1 Phosphorus compounds containing P—P bonds 275
8.1.1 Structural Characteristics and Physical Properties of Phosphorus Compounds Containing PP Bonds 275
8.1.2 The Chemical Properties of Diphosphyrins 277
8.1.3 Synthesis of Diphosphine 281
8.2 Transition Metal Complexes of Diphosphine 284
8.2.1 Types of Transition Metal Complexes of Diphosphine 284
8.2.2 Diphosphine Complex 31P NMR Spectroscopy 288
8.2.3 The Chemical Properties of Diphosphine Transition Metal Complexes 289
8.3 Phosphorus compounds containing P—As bonds 290
8.3.1 Physical Properties of Phosphorus Arsenide 290
8.3.2 The Chemical Properties of Phosphorus Arsenide 291
8.3.3 Synthesis of Phosphorus Arsenide Compounds 292
8.3.4 Phosphorus Arsenide Complexes 293
Reference 294

Chapter 9: High-Performance Phosphine and Phosphine Salts 296
9.1 Five-coordination Phosphines 296
9.1.1 Molecular Structure Characteristics and Physical Properties of Pentad Phosphines 296
9.1.2 The Chemical Properties of Pentadichlorophosphate 298
9.1.3 Preparation of Pentad Phosphines 300
9.1.4 Examples of the Synthesis of Pentadentate Phosphines 303
9.2 Six-coordination phosphane (salt) 303
9.2.1 Structural Characteristics and Physical Properties of Six-Coordination Phosphines (Salts) 303
9.2.2 The Chemical Properties of Six-Coordination Phosphines 306
9.2.3 Synthesis of Six-Coordination Phosphine Salts 307
9.2.4 Synthesis of Neutral Six-Coordination Phosphorus Compounds 308
Reference 310

Chapter 10 Organophosphorus Active Intermediates 312
10.1 Phosphorus Radical 312
10.1.1 Seven Electron Phosphorus Free Radicals 312
10.1.2 Nine-electron phosphorus radical 314
10.2 Phosphorus Positive Ions Compounds 316
10.2.131P Nuclear Magnetic Resonance Spectrum 316
10.2.2 The Chemical Properties of Phosphorus Positive Ions 317
10.2.3 Synthesis of Phosphorus Positive Ions 318
Reference 318

CD content introduction, the table of contents is as follows:

1 Organometallic compounds and emission switching organic electroluminescent properties
2 Waterborne dispersions of organophosphorus compounds and a fireproof processing method using such dispersions
3 Organometallic compounds and emission switching organic electroluminescent properties
4 A polylactic acid composition containing sulfonic acid compounds and phosphorus-containing organic compounds, and its preparation method
5 Organic light-emitting diodes containing carbene-transition metal complexes emitters and at least one compound selected from dimethylsilane carbazoles, dimethylsilane dibenzenes, dimethylsilane dibenzo-thienones, dimethylsilane dibenzo-phospholanes, dimethylsilane dibenzo-thienones S-oxides, and dimethylsilane dibenzo-thienones S,S-dioxides
6 Phosphonitrile compounds substituted by other compounds, as well as their uses as flame-retardant additives in organic polymers
7 Methods for Continuous Preparation of Organophosphorus Compounds and Their Applications
8 Acylglycerophosphorus Compounds and Their Applications
9 Organic light-emitting diodes containing dimethyldisilazacyclobenzene compounds selected from dimethyldisilazacyclobenzene, dimethyldisilazabenzene, dimethyldisilazabenzothiophene, dimethyldisilazabenzophospholane, dimethyldisilazabenzothiophene S-oxides, and dimethyldisilazabenzothiophene S,S-dioxides
10 Phosphazaphthalene compounds and organic light-emitting diodes using these phosphazaphthalene compounds
11 Using organophosphorus sulfur compounds to inhibit the corrosion of high-temperature naphthenic acids
12 Compounds containing phosphorescent units, luminescent polymers containing these compounds, and organic light-emitting devices
13 Synthesis Method of Flotation Agents for Organophosphorus Compounds and Organophosphorus Flotation Agents
14 Organic phosphorus compounds with phosphate-phosphite bonds, and flame-retardant fibers and compositions using them
15 Organic light-emitting devices using compounds with carrier transport properties and phosphorescence properties
16 Methods for preparing organophosphorus compounds containing halogens
17 A Thiazole-type Organophosphorus Compound and Its Synthesis Method and Application
18 Thiazole organic phosphorus compounds and their synthesis and application
19 Methods for preparing organophosphorus compounds
20 Organophosphorus compounds, their preparation processes, and compositions containing organophosphorus insecticides, acaricides, or nematicides
Method for alkyiding olefins in the presence of organophosphorus compounds
22 Organometallic luminescent elements and their manufacturing methods, as well as phosphorus-containing organic compounds and their preparation methods
23 Tannin Organic Phosphorus Compounds and Their Applications
Preparation of trivalent organophosphorus compounds
25 Organic phosphorus compounds with phosphoester-phosphite bonds, and flame-retardant polyester fibers and flame-retardant polyurethane resin compositions using them
26 Phosphorus-containing organic compound-modified low melting point alloy nanoparticles and their preparation methods
27 Lithium-ion battery electrolytes containing organic phosphorus compounds and the composition of the battery
28 Phosphorescent compounds, phosphorescent compositions, and organic light-emitting elements
29 Organophosphorus compounds used to activate γ/δT-cells
A pesticidal composition containing methylamine amino avermectin and organophosphorus compounds.
31 A powder injection composition for treating organophosphorus compound poisoning
32 Organometallic compounds and emission switching organic electroluminescent properties
33 Methods for Preparing Water-Soluble Sulfonated Organophosphorus Compounds
34 Applications of Organophosphorus Compounds for the Prevention or Treatment of Infections
35 Organophosphorus Compounds and Their Uses
36 Organophosphorus Compounds and Their Applications
37 The use of organophosphorus compounds in the preparation of drugs for the treatment or preventive treatment of infections, or as fungicides, bactericides, or herbicides in plants
A pesticide composition consisting of organophosphorus compounds and pesticides containing pyrazolyl groups.
39 Organic phosphorus compounds used in composite materials with reinforcing agents
40 Organophosphorus Compounds and Their Uses
41 The Application of Organophosphorus Compounds in the Treatment and Preventive Treatment of Infections
42 Methods for preparing organic phosphine compounds and organic phosphine compositions, as well as polyester compositions and their preparation methods
Methods for preparing phosphorus-containing organic compounds
Method for removing organophosphorus compounds contained in gases or liquids
45 Insecticides containing organic nitrogen and organic phosphorus compounds, their preparation methods, and uses
46 Organophosphorus compounds
Methods for treating organic compounds containing halogens, phosphorus, sulfur, and/or metal elements
48 Wastewater treatment methods containing organic phosphorus compounds, especially sulfonated arylphosphines
Method for separating organophosphorus compounds and other impurities from dilute solutions
50 Organophosphorus compounds and their preparation methods related to insecticides, acaricides, and nematicides
51 Safe application of the herbicide Kromakon using organophosphorus compounds
52 Transition metal compounds used in complex decomposition reactions, containing cyclic phosphorus ligands and cyclic organic ligands
53 Compounds Used for Preparing Organophosphorescent Materials and Their Preparation Methods
54 A type of phosphoramide organic phosphorus compound
55 Organometallic compounds and emissive switching organic electroluminescent lighting
56 Organometallic compounds and emissive switching organic electroluminescent properties